Gate-opening effect in ZIF-8: The first experimental proof using inelastic neutron scattering

M. E. Casco; Y. Q. Cheng; L. L. Daemen; D. Fairen-Jimenez; E. V. Ramos-Fernández; A. J. Ramirez-Cuesta; J. Silvestre-Albero

doi:10.1039/c5cc10222g

Gate-opening effect in ZIF-8: The first experimental proof using inelastic neutron scattering

M. E. Casco
, Y. Q. Cheng
, L. L. Daemen
, D. Fairen-Jimenez
, E. V. Ramos-Fernández
, A. J. Ramirez-Cuesta
, J. Silvestre-Albero

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

132 Citas (Scopus)

Resumen

The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH₃ groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N₂ pressure.

Idioma original	Inglés
Páginas (desde-hasta)	3639-3642
Número de páginas	4
Publicación	Chemical Communications
Volumen	52
N.º	18
DOI	https://doi.org/10.1039/c5cc10222g
Estado	Publicada - 2016
Publicado de forma externa	Sí

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title = "Gate-opening effect in ZIF-8: The first experimental proof using inelastic neutron scattering",

abstract = "The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.",

author = "Casco, \{M. E.\} and Cheng, \{Y. Q.\} and Daemen, \{L. L.\} and D. Fairen-Jimenez and Ramos-Fern{\'a}ndez, \{E. V.\} and Ramirez-Cuesta, \{A. J.\} and J. Silvestre-Albero",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

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doi = "10.1039/c5cc10222g",

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T1 - Gate-opening effect in ZIF-8

T2 - The first experimental proof using inelastic neutron scattering

AU - Casco, M. E.

AU - Cheng, Y. Q.

AU - Daemen, L. L.

AU - Fairen-Jimenez, D.

AU - Ramos-Fernández, E. V.

AU - Ramirez-Cuesta, A. J.

AU - Silvestre-Albero, J.

PY - 2016

Y1 - 2016

N2 - The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.

AB - The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.

UR - https://www.scopus.com/pages/publications/84959181423

U2 - 10.1039/c5cc10222g

DO - 10.1039/c5cc10222g

M3 - Artículo

AN - SCOPUS:84959181423

SN - 1359-7345

VL - 52

SP - 3639

EP - 3642

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Gate-opening effect in ZIF-8: The first experimental proof using inelastic neutron scattering

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